Classes of cyclization (3-exo-tet)


Click the structures and reaction arrows in sequence to view the 3D models and animations respectively

The ring being formed has three members; the breaking C-Br bond is outside the new ring (exo); the C carrying Br is a tetrahedral (sp3) atom (tet).


Jmol.jmolButton(jmolApplet0, ‘load ../model/baldwins_rule/classes_cyclization/1/1.xyz;wireframe 0.1;spacefill 20%;moveto 0.0 556 -831 -35 5.83;select all;set labelOffset 0 0;font label 18 ariel bold;color label orange;connect 1.8 2.2 (atomno=2) (atomno=5) PARTIAL;connect 2.29 2.68 (atomno=2) (atomno=6) PARTIAL;wireframe 0.1;select atomno=4;label 2;select atomno=2;label 3;select atomno=5 and model=1.1;label 1:;select atomno=5 and model=1.2;label 1:;select atomno=5 and model=1.3;label 1:;select atomno=5 and model=1.4;label 1:;select atomno=5 and model=1.5;label 1:;select atomno=5 and model=1.6;label 1:;select atomno=5 and model=1.7;label 1:;select atomno=5 and model=1.8;label 1:;select atomno=5 and model=1.9;label 1:;select atomno=5 and model=1.10;label 1:;select atomno=5 and model=1.11;label 1:;select atomno=5 and model=1.12;label 1:;select atomno=5 and model=1.13;label 1:;select atomno=5 and model=1.14;label 1:;select atomno=5 and model=1.15;label 1:;select atomno=5 and model=1.16;label 1:;select atomno=5 and model=1.17;label 1:;select atomno=5 and model=1.18;label 1:;select atomno=5 and model=1.19;label 1;select atomno=5 and model=1.20;label 1;select atomno=5 and model=1.21;label 1;select atomno=5 and model=1.22;label 1;select atomno=5 and model=1.23;label 1;select atomno=5 and model=1.24;label 1;select atomno=5 and model=1.25;label 1;select atomno=5 and model=1.26;label 1;select atomno=5 and model=1.27;label 1;select atomno=5 and model=1.28;label 1+;select atomno=5 and model=1.29;label 1+;select atomno=5 and model=1.30;label 1+;select atomno=5 and model=1.31;label 1+;select atomno=5 and model=1.32;label 1+;select atomno=5 and model=1.33;label 1+;select atomno=6 and model=1.28;label -;select atomno=6 and model=1.29;label -;select atomno=6 and model=1.30;label -;select atomno=6 and model=1.31;label -;select atomno=6 and model=1.32;label -;select atomno=6 and model=1.33;label -;select (atomno=5);lcaocartoon color translucent green scale 1.1 create “lp”;select atomno=2 and model=1.1;lcaocartoon color translucent yellow scale 1.1 create “-sp3b”;select atomno=2 and model=1.2;lcaocartoon color translucent yellow scale 1.1 create “-sp3b”;select atomno=2 and model=1.3;lcaocartoon color translucent yellow scale 1.1 create “-sp3b”;select atomno=2 and model=1.4;lcaocartoon color translucent yellow scale 1.1 create “-sp3b”;select atomno=2 and model=1.5;lcaocartoon color translucent yellow scale 1.1 create “-sp3b”;select atomno=2 and model=1.6;lcaocartoon color translucent yellow scale 1.1 create “-sp3b”;select atomno=2 and model=1.7;lcaocartoon color translucent yellow scale 1.1 create “-sp3b”;select atomno=2 and model=1.8;lcaocartoon color translucent yellow scale 1.1 create “-sp3b”;select atomno=2 and model=1.9;lcaocartoon color translucent yellow scale 1.1 create “-sp3b”;select atomno=2 and model=1.10;lcaocartoon color translucent yellow scale 1.1 create “-sp3b”;select atomno=2 and model=1.11;lcaocartoon color translucent yellow scale 1.1 create “-sp3b”;select atomno=2 and model=1.12;lcaocartoon color translucent yellow scale 1.1 create “-sp3b”;select atomno=2 and model=1.13;lcaocartoon color translucent yellow scale 1.1 create “-sp3b”;select atomno=2 and model=1.14;lcaocartoon color translucent yellow scale 1.1 create “-sp3b”;select atomno=2 and model=1.15;lcaocartoon color translucent yellow scale 1.1 create “-sp3b”;select atomno=2 and model=1.16;lcaocartoon color translucent yellow scale 1.1 create “-sp3b”;select atomno=2 and model=1.17;lcaocartoon color translucent yellow scale 1.1 create “-sp3b”;select atomno=2 and model=1.18;lcaocartoon color translucent yellow scale 1.1 create “-sp3b”;select atomno=6 and model=1.1;lcaocartoon color translucent purple scale 1.1 create “sp2a”;select atomno=6 and model=1.2;lcaocartoon color translucent purple scale 1.1 create “sp2a”;select atomno=6 and model=1.3;lcaocartoon color translucent purple scale 1.1 create “sp2a”;select atomno=6 and model=1.4;lcaocartoon color translucent purple scale 1.1 create “sp2a”;select atomno=6 and model=1.5;lcaocartoon color translucent purple scale 1.1 create “sp2a”;select atomno=6 and model=1.6;lcaocartoon color translucent purple scale 1.1 create “sp2a”;select atomno=6 and model=1.7;lcaocartoon color translucent purple scale 1.1 create “sp2a”;select atomno=6 and model=1.8;lcaocartoon color translucent purple scale 1.1 create “sp2a”;select atomno=6 and model=1.9;lcaocartoon color translucent purple scale 1.1 create “sp2a”;select atomno=6 and model=1.10;lcaocartoon color translucent purple scale 1.1 create “sp2a”;select atomno=6 and model=1.11;lcaocartoon color translucent purple scale 1.1 create “sp2a”;select atomno=6 and model=1.12;lcaocartoon color translucent purple scale 1.1 create “sp2a”;select atomno=6 and model=1.13;lcaocartoon color translucent purple scale 1.1 create “sp2a”;select atomno=6 and model=1.14;lcaocartoon color translucent purple scale 1.1 create “sp2a”;select atomno=6 and model=1.15;lcaocartoon color translucent purple scale 1.1 create “sp2a”;select atomno=6 and model=1.16;lcaocartoon color translucent purple scale 1.1 create “sp2a”;select atomno=6 and model=1.17;lcaocartoon color translucent purple scale 1.1 create “sp2a”;select atomno=6 and model=1.18;lcaocartoon color translucent purple scale 1.1 create “sp2a”;anim mode once;frame 1;anim on;set echo bottom center;font echo 16 sansserif bold;echo Plays once through, then stops;’,
“View orbital animation”);

Back to previous page

K. Gilmore and I. V. Alabugin, Chem. Rev., 2011, 111, 6513–6556.

810

()

How useful was this page?

Click on a star to rate it!

Average rating / 5. Vote count:

No votes so far! Be the first to rate this page.

As you found this page useful...

Follow us on social media!

We are sorry that this page was not useful for you!

Let us improve this page!

Tell us how we can improve this page (in your own language if you prefer)? If you would like a response, please include your email address e.g. [email protected]

Provided by the