Shift in Electron Density in d-d Transitions

shifts in electron density that accompany the two d-d transitions

Electron movement is symbolised by shading of the orbitals.
The shifts in electron density that accompany the two transitions discussed in the text. There is a considerable relocation of electron density towards the ligands on the z-axis in (a), but a much less substantial relocation in (b).

Orbital-orbital overlap and SALC Homepage

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