Rearrangements – Diastereoisomer 3

NOTE: Important charges and non-bonding electrons are shown throughout the animation except during the transition phase

^{Click the structures and reaction arrows in sequence to view the 3D models and animations respectively}

With the leaving group –N₂⁺ axial the atom best placed to migrate is the green hydrogen. This hydrogen is anti-periplanar to the leaving group so it migrates.

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