Rearrangements – Diastereoisomer 3

NOTE: Important charges and non-bonding electrons are shown throughout the animation except during the transition phase

Click the structures and reaction arrows in sequence to view the 3D models and animations respectively

With the leaving group –N2+ axial the atom best placed to migrate is the green hydrogen. This hydrogen is anti-periplanar to the leaving group so it migrates.

Back to previous page

P. Lewis, S. Middleton, M. Rosser and L. Stock, Aust. J. Chem., 1980, 33, 1049.

Z.-L. Song, C.-A. Fan and Y.-Q. Tu, Chem. Rev., 2011, 111, 7523–7556.

 

 

How useful was this page?

Click on a star to rate it!

Average rating / 5. Vote count:

As you found this post useful...

Follow us on social media!

We are sorry that this page was not useful for you!

Let us improve this page!

Provided by the