NiCN53- – trigonal bipyramidal or square pyramidal

5-coordinate [Ni(CN)5]3− complex can adopt either the trigonal bipyramidal geometry (left) or the square pyramidal geometry (right),

Ni(CN)53- trigonal bipyamidNI(CN)53- square based pyramid

The 5-coordinate Ni(CN)53- complex can adopt either the trigonal bipyramidal geometry (left) or the square pyramidal geometry (right), depending on the cation in the compound.

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