Interactions between Allyl Molecular Orbitals and Metal d Orbitals

The allyl π system molecular orbitals bond to the metal d orbital with the correct symmetry. The lowest energy MO forms a σ bond to dz2. The HOMO behaves as a π donor into the dxz whilst the LUMO a π acceptor from the dyz.

Allyl

View Allyl Molecular Orbitals here

Explore Metal-Ligand bonding with other molecules

Carbon Monoxide | Phosphine | Hydrogen | Ethylene | Cyclobutadiene | Butadiene | Benzene | Allyl | Cyclopentadienyl | Carbene

 

 

© 2008-2019 The University of Liverpool

Provided by the