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Small (300 px) Medium (400 px) Large (500 px) /> Click the structures and reaction arrows in sequence to view the 3D models and animations respectively The butyllithium removes a proton from the relatively acidic alpha carbon. The carbanion attacks the ketone which yields a oxygen anion. The oxygen anion attacks the silicon to form a 4-membered ring which then opens to yield a vinyl silane and a silyl alcohol - a Peterson elimination.
Click the structures and reaction arrows in sequence to view the 3D models and animations respectively
The butyllithium removes a proton from the relatively acidic alpha carbon. The carbanion attacks the ketone which yields a oxygen anion. The oxygen anion attacks the silicon to form a 4-membered ring which then opens to yield a vinyl silane and a silyl alcohol - a Peterson elimination.